Rapid Synthesis of Block and Cyclic Copolymers via Click Chemistry in the Presence of Copper Nanoparticles.

نویسندگان

  • Eric D Pressly
  • Roey J Amir
  • Craig J Hawker
چکیده

A new method for the rapid and efficient coupling of homopolymers to yield di- and triblock copolymers as well as cyclic polymers using the 3 + 2 π Huisgen copper catalyzed cyclo-addition reaction has been developed. This facile method utilizes commercially available Cu nanoparticles that are tolerant to O(2), easily removable and recyclable.

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عنوان ژورنال:
  • Journal of polymer science. Part A, Polymer chemistry

دوره 49 3  شماره 

صفحات  -

تاریخ انتشار 2011